Chirality and domain growth in the gyroid mesophase

نویسنده

  • P. V. Coveney
چکیده

We describe the first dynamical simulations of domain growth during the self-assembly of the gyroid mesophase from a ternary amphiphilic mixture, using the lattice Boltzmann method. The gyroid is a chiral structure; we demonstrate that, for a symmetric amphiphile with no innate preference for leftor right-handed morphologies, the selfassembly process may give rise to a racemic mixture of domains. We use measurements of the averaged mean curvature to analyse the behaviour of domain walls, and suggest that diffusive domain growth may be present in this system.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Non-Newtonian behaviour of the gyroid mesophase: A lattice-Boltzmann study

We use a lattice-Boltzmann (LB) kinetic scheme for modelling amphiphilic mixtures to impose Couette flow on self-assembled gyroid mesophase. We report evidence of non-Newtonian behaviour (“shear thinning”) and we show that the particular lack of inversion symmetry which characterizes the gyroid unit cell does not quantitatively affect the flow dynamics beyond a certain predictable shear velocit...

متن کامل

On the origin of chirality in nanoplasmonic gyroid metamaterials.

Metallic single gyroids, a new class of self-assembled nanoplasmonic metamaterials, are analyzed on the basis of a tri-helical metamaterial model. The physical mechanisms underlying the chiral optical behavior of the nanoplasmonic single gyroid are identified and it is shown that the optical chirality in this metallic structure is primarily determined by structural chirality and the connectivit...

متن کامل

Coexistence of both gyroid chiralities in individual butterfly wing scales of Callophrys rubi.

The wing scales of the Green Hairstreak butterfly Callophrys rubi consist of crystalline domains with sizes of a few micrometers, which exhibit a congenitally handed porous chitin microstructure identified as the chiral triply periodic single-gyroid structure. Here, the chirality and crystallographic texture of these domains are investigated by means of electron tomography. The tomograms unambi...

متن کامل

Emergence of rheological properties in lattice Boltzmann simulations of gyroid mesophases

– We use a lattice Boltzmann (LB) kinetic scheme for modelling amphiphilic fluids that correctly predicts rheological effects in flow. No macroscopic parameters are included in the model. Instead, three-dimensional hydrodynamic and rheological effects are emergent from the underlying particulate conservation laws and interactions. We report evidence of shear thinning and viscoelastic flow for a...

متن کامل

Self-assembly in block polyelectrolytes.

The self-consistent field theory (SCFT) complemented with the Poisson-Boltzmann equation is employed to explore self-assembly of polyelectrolyte copolymers composed of charged blocks A and neutral blocks B. We have extended SCFT to dissociating triblock copolymers and demonstrated our approach on three characteristic examples: (1) diblock copolymer (AB) melt, (2) symmetric triblock copolymer (A...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2006